Solid-state structure and electronic states of hydrogen-bonded dimer of pyridyl-substituted tetrathiafulvalene salted with PF6−-Reference-Cited by-同舟云学术

Solid-state structure and electronic states of hydrogen-bonded dimer of pyridyl-substituted tetrathiafulvalene salted with PF6−

Published:2017 Issue:11 Volume:7 Page:6236-6241
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Kanetou Tomoaki¹²³⁴,Tsunashima Ryo¹²³⁴^ORCID,Hoshino Norihisa⁵⁶⁷⁴,Akutagawa Tomoyuki⁵⁶⁷⁴

Affiliation:

1. Graduate School of Science and Engineering

2. Yamaguchi University

3. Yamaguchi

4. Japan

5. Institute of Multidisciplinary Research for Advanced Materials (IMRAM)

6. Tohoku University

7. Sendai 980-8577

Abstract

Our results clarified uniqueness in hydrogen bonding TTFPy dimer in which proton in hydrogen bond was thermally fluctuated. In addition, the fluctuation was coupled with π-electronic systems of TTF moiety where electric dipole moment was amplified.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/RA/C6RA27814K

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