Remote C(sp3)–H functionalization via catalytic cyclometallation: beyond five-membered ring metallacycle intermediates

Author:

Mingo Mario Martínez1,Rodríguez Nuria12ORCID,Arrayás Ramón Gómez12ORCID,Carretero Juan C.12ORCID

Affiliation:

1. Department of Organic Chemistry, Universidad Autónoma de Madrid, c/Fco. Tomás y Valiente 7, Cantoblanco 28049, Madrid, Spain

2. Institute for Advanced Research in Chemical Sciences (IAdChem), Universidad Autónoma de Madrid (UAM), Spain

Abstract

Despite impressive recent momentum gained in C(sp3)–H activation, achieving high regioselectivity in molecules containing different C–H bonds with similar high energy without abusing tailored substitution remains as one of the biggest challenges.

Funder

Ministerio de Economía y Competitividad

Ministerio de Ciencia e Innovación

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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