Stress-induced colouration and crosslinking of polymeric materials by mechanochemical formation of triphenylimidazolyl radicals-Reference-Cited by-同舟云学术

Stress-induced colouration and crosslinking of polymeric materials by mechanochemical formation of triphenylimidazolyl radicals

Published:2016 Issue:55 Volume:52 Page:8608-8611
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Verstraeten F.¹²³⁴⁵,Göstl R.¹²³⁴⁵^ORCID,Sijbesma R. P.¹²³⁴⁵

Affiliation:

1. Technische Universiteit Eindhoven

2. Molecular Science and Technology

3. Group Supramolecular Polymer Chemistry

4. 5600 MB Eindhoven

5. The Netherlands

Abstract

Subjecting hexaarylbiimidazole in polymer architectures to stress generates coloured triphenylimidazolyl radicals that initiate secondary radical reactions unifying stress-sensing and damage-repair.

Funder

Deutsche Forschungsgemeinschaft

Ministerie van Onderwijs, Cultuur en Wetenschappen

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CC/C6CC04312G

Reference36 articles.

1. Mechanochemistry: The Mechanical Activation of Covalent Bonds

2. Mechanically-Induced Chemical Changes in Polymeric Materials

3. Mechanochemical remodeling of synthetic polymers

4. Mechanocatalysis: forcing latent catalysts into action

5. Polymer Mechanochemistry: From Destructive to Productive

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