Stabilizing lead halide perovskites with quaternary ammonium cations: the case of tetramethylammonium lead iodide

Author:

Ciccioli Andrea1234ORCID,Panetta Riccardo1234ORCID,Luongo Alessio1234,Brunetti Bruno56234ORCID,Vecchio Ciprioti Stefano7284ORCID,Mele Maria Luisa92104,Latini Alessandro1234ORCID

Affiliation:

1. Dipartimento di Chimica

2. Sapienza Università di Roma

3. 00185 Roma

4. Italy

5. Consiglio Nazionale delle Ricerche – Istituto per lo Studio dei Materiali Nanostrutturati

6. c/o Dipartimento di Chimica

7. Dipartimento S.B.A.I.

8. 00161 Roma

9. Dipartimento I.C.M.A.

10. 00184 Roma

Abstract

N(CH3)4PbI3 is much more stable than CH3NH3PbI3, both kinetically and thermodynamically, and much less prone to water-induced degradation; the use of quaternary ammonium cations may be effective to produce more stable lead halide perovskites.

Funder

Sapienza Università di Roma

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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