Synthesis, characterization, X-ray and electronic structures of diethyl ether and 1,2-dimethoxyethane adducts of molybdenum(<scp>iv</scp>) chloride and tungsten(<scp>iv</scp>) chloride-Reference-Cited by-同舟云学术

Synthesis, characterization, X-ray and electronic structures of diethyl ether and 1,2-dimethoxyethane adducts of molybdenum(iv) chloride and tungsten(iv) chloride

Published:2022 Issue:20 Volume:51 Page:7856-7863
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shaw Thomas E.¹²^ORCID,Diethrich Timothy J.³^ORCID,Stern Charlotte L.⁴^ORCID,Scott Brian L.⁵^ORCID,Jurca Titel¹²^ORCID,Gilbert Thomas M.⁶^ORCID,Sattelberger Alfred P.¹^ORCID

Affiliation:

1. Department of Chemistry, University of Central Florida, Orlando, FL 32816, USA

2. Renewable Energy and Chemical Transformations (REACT) Cluster, University of Central Florida, Orlando, FL 32816, USA

3. Department of Chemistry and Biochemistry, University of Maryland, College Park, MD 20742, USA

4. Department of Chemistry, Northwestern University, Evanston, IL 60208, USA

5. Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA

6. Department of Chemistry and Biochemistry, Northern Illinois University, DeKalb, IL 60115, USA

Abstract

Facile routes to MCl4(dme) M = Mo, W. Improved syntheses and characterizations.

Funder

University of Central Florida

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00787H

Reference54 articles.

1. Four-Coordinate Mo(II) as (silox)2Mo(PMe3)2and Its W(IV) Congener (silox)2HW(η2-CH2PMe2)(PMe3) (silox =tBu3SiO)

2. Molybdenum and Tungsten Structural Differences are Dependent on ndz2/(n + 1)s Mixing: Comparisons of (silox)3MX/R (M = Mo, W; silox = tBu3SiO)

3. Molybdenum and Tungsten Complexes That Contain the Diamidoamine Ligands [(C6F5NCH2CH2)2NMe]2-, [(3,4,5-C6H2F3NCH2CH2)2NMe]2-, and [(3-CF3C6H4NCH2CH2)2NMe]2-

4. Syntheses and reactions of ansa-[2,2-bis(η-cyclopentadienyl)propane]-tungsten and -molybdenum compounds

5. Syntheses and Molecular Structures of New Calix[4]arene Molybdenum and Tungsten Complexes

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