Guest exchange in a biomimetic Zn<sup>II</sup> cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes-Reference-Cited by-同舟云学术

Guest exchange in a biomimetic Zn^II cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes

Published:2023 Issue:19 Volume:10 Page:5772-5781
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Nyssen N.¹²,Giraud N.¹^ORCID,Wouters J.³,Jabin I.²^ORCID,Leherte L.³^ORCID,Reinaud O.¹^ORCID

Affiliation:

1. Laboratoire de Chimie et de Biochimie Pharmacologiques et Toxicologiques, CNRS UMR 8601 Université Paris Cité, 45 Rue des Saints Pères, 75006 Paris, France

2. Laboratoire de Chimie Organique, Université Libre de Bruxelles (ULB), Avenue F. D. Roosevelt 50, CP160/06, B-1050 Brussels, Belgium

3. Laboratory of Structural Biological Chemistry, Unit of Theoretical and Structural Physical Chemistry, Department of Chemistry, NAmur Research Institute for LIfe Sciences (NARILIS), Namur Institute of Structured Matter (NISM), NAmur MEdicine & Drug Innovation Center (NAMEDIC), University of Namur, Rue de Bruxelles 61, B-5000 Namur, Belgium

Abstract

The kinetics of ligand exchange at a ZnII center confined in a biomimetic environment is studied.

Funder

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

Université de Paris

Université Libre de Bruxelles

Fonds De La Recherche Scientifique - FNRS

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link