Guest exchange in a biomimetic ZnII cavity-complex: kinetic control by a catalytic water, through pore selection, 2nd sphere assistance, and induced-fit processes

Author:

Nyssen N.12,Giraud N.1ORCID,Wouters J.3,Jabin I.2ORCID,Leherte L.3ORCID,Reinaud O.1ORCID

Affiliation:

1. Laboratoire de Chimie et de Biochimie Pharmacologiques et Toxicologiques, CNRS UMR 8601 Université Paris Cité, 45 Rue des Saints Pères, 75006 Paris, France

2. Laboratoire de Chimie Organique, Université Libre de Bruxelles (ULB), Avenue F. D. Roosevelt 50, CP160/06, B-1050 Brussels, Belgium

3. Laboratory of Structural Biological Chemistry, Unit of Theoretical and Structural Physical Chemistry, Department of Chemistry, NAmur Research Institute for LIfe Sciences (NARILIS), Namur Institute of Structured Matter (NISM), NAmur MEdicine & Drug Innovation Center (NAMEDIC), University of Namur, Rue de Bruxelles 61, B-5000 Namur, Belgium

Abstract

The kinetics of ligand exchange at a ZnII center confined in a biomimetic environment is studied.

Funder

Ministère de l'Education Nationale, de l'Enseignement Superieur et de la Recherche

Université de Paris

Université Libre de Bruxelles

Fonds De La Recherche Scientifique - FNRS

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Cited by 1 articles. 订阅此论文施引文献 订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献

1. TMPA‐based Cavitary Cobalt (II) Funnel Complexes;European Journal of Inorganic Chemistry;2024-07-19

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