Unlocking catalytic potential: a rhodium(<scp>ii</scp>)-based coordination polymer for efficient carbene transfer reactions with donor/acceptor diazoalkanes-Reference-Cited by-同舟云学术

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Unlocking catalytic potential: a rhodium(ii)-based coordination polymer for efficient carbene transfer reactions with donor/acceptor diazoalkanes

Published:2024 Issue:57 Volume:60 Page:7327-7330
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Empel Claire¹^ORCID,Fetzer Marcus N. A.²,Sasmal Suman¹,Strothmann Till²^ORCID,Janiak Christoph²^ORCID,Koenigs Rene M.¹^ORCID

Affiliation:

1. Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany

2. Institut für Anorganische Chemie und Strukturchemie, Heinrich-Heine-Universität Düsseldorf, Universitätsstraße 1, 40225 Düsseldorf, Germany

Abstract

Herein, we report the use of a molecular-defined rhodium(ii) coordination polymer (Rh-CP) as a heterogeneous, recyclable catalyst in carbene transfer reactions.

Funder

Deutsche Forschungsgemeinschaft

RWTH Aachen University

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC01386G

Reference50 articles.

1. Dirhodium(II,II) Paddlewheel Complexes

2. Locking the Conformation of a Paddlewheel Rhodium Complex: Design, Synthesis, and Applications in Catalytic Nitrene Transfers

3. Synthesis and crystal structures of rhodium acetate paddle‐wheel complexes with anchor group‐functionalised and hydrogen bond‐supported axial ligands

4. Modern Organic Synthesis with α-Diazocarbonyl Compounds

5. Donor−Acceptor-Substituted Cyclopropane Derivatives and Their Application in Organic Synthesis

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