Non-stackable molecules assemble into porous crystals displaying concerted cavity-changing motions
Author:
Affiliation:
1. Department of Chemistry
2. Seoul National University
3. Seoul 08826
4. Korea
5. Ulsan National Institute of Science and Technology (UNIST)
6. Ulsan 44919
7. Pohang Accelerator Laboratory
8. Pohang 37673
Abstract
Like non-collapsible open voids within stacks of steel H-beams, a non-covalent assembly of three-dimensional aromatics produces porous crystals. Concerted motions of the molecular H-beams open and close the cavities in response to external stimuli.
Funder
National Research Foundation
Samsung Science and Technology Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC01163D
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