Reactivity of an amidinato silylene and germylene toward germanium(ii), tin(ii) and lead(ii) halides-Reference-Cited by-同舟云学术

Reactivity of an amidinato silylene and germylene toward germanium(ii), tin(ii) and lead(ii) halides

Published:2017 Issue:11 Volume:46 Page:3642-3648
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Shan Yu-Liang¹²³⁴,Leong Bi-Xiang¹²³⁴^ORCID,Xi Hong-Wei⁵⁴,Ganguly Rakesh¹²³⁴,Li Yongxin¹²³⁴,Lim Kok Hwa⁵⁴,So Cheuk-Wai¹²³⁴^ORCID

Affiliation:

1. Division of Chemistry and Biological Chemistry

2. School of Physical and Mathematical Sciences

3. Nanyang Technological University

4. Singapore

5. Singapore Institute of Technology

Abstract

The reaction of the amidinato silicon(ii) 1 and germanium(ii) amide 4 with PbBr₂ and SnCl₂ afforded the amidinato silylene–dibromoplumbylene 3 and germylene–dichlorostannylene 6 adducts, respectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/DT/C7DT00051K

Reference82 articles.

1. V. Y. Lee and A.Sekiguchi, Organometallic Compounds of Low-Coordinate Si, Ge, Sn and Pb: From Phantom Species to Stable Compounds, Wiley, Chichester, U.K., 2010

2. Heavier group 14 complexes with anionic P-donor ligands

3. Chemical Tricks To Stabilize Silanones and Their Heavier Homologues with EO Bonds (E=Si-Pb): From Elusive Species to Isolable Building Blocks

4. Group 14 Hydrides with Low Valent Elements for Activation of Small Molecules

5. Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

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