Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide-Reference-Cited by-同舟云学术

Visible light photocatalytic one pot synthesis of Z-arylvinyl halides from E-arylvinyl acids with N-halosuccinimide

Published:2022 Issue:7 Volume:12 Page:3931-3934
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Yu Qiong¹,Yu Kun Yi¹,Xu Cai Feng¹,Wong Man-Kin¹²^ORCID

Affiliation:

1. The Hong Kong Polytechnic University Shenzhen Research Institute, Shenzhen, 518057, China

2. State Key Laboratory of Chemical Biology and Drug Discovery, Department of Applied Biology and Chemical Technology, The Hong Kong Polytechnic University, Hung Hum, Hong Kong, China

Abstract

An efficient visible light photocatalytic strategy to synthesize Z-arylvinyl halides from E-arylvinyl acids using N-halosuccinimide through a sequential halodecarboxylation/photoisomerization with up to >99/1 Z/E ratio and 86% yield under mild reaction conditions.

Funder

Science, Technology and Innovation Commission of Shenzhen Municipality

Hong Kong Polytechnic University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RA/D1RA08753C

Reference56 articles.

1. Visible light photocatalysis as a greener approach to photochemical synthesis

2. Engaging unactivated alkyl, alkenyl and aryl iodides in visible-light-mediated free radical reactions

3. Visible-Light Photoredox Catalysis

4. Visible Light Photoredox Catalysis with Transition Metal Complexes: Applications in Organic Synthesis

5. The Photocatalyzed Meerwein Arylation: Classic Reaction of Aryl Diazonium Salts in a New Light

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