A radical Smiles rearrangement difunctionalization of activated alkenes <i>via</i> desulfonylation and insertion of sulfur dioxide relay strategy-Reference-Cited by-同舟云学术

A radical Smiles rearrangement difunctionalization of activated alkenes via desulfonylation and insertion of sulfur dioxide relay strategy

Published:2024 Issue:11 Volume:26 Page:6774-6778
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Tian Si-Wei¹,Luo Zhen-Tao¹,Xiong Bi-Quan¹^ORCID,Tang Ke-Wen¹^ORCID,Huang Peng-Fei¹^ORCID,Liu Yu¹^ORCID

Affiliation:

1. Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang 414006, China

Abstract

A novel and attractive photochemical difunctionalization of N-tosyl acrylamide for constructing alkylsulfonylated oxindoles and amides with excellent substrate adaptability via a radical Smiles rearrangement strategy is described.

Funder

National Natural Science Foundation of China

Education Department of Hunan Province

Natural Science Foundation of Hunan Province

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D4GC00186A

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