Direct conjugate alkylation of α,β-unsaturated carbonyls by TiIII-catalysed reductive umpolung of simple activated alkenes-Reference-Cited by-同舟云学术

Direct conjugate alkylation of α,β-unsaturated carbonyls by TiIII-catalysed reductive umpolung of simple activated alkenes

Published:2016 Issue:24 Volume:14 Page:5673-5682
ISSN:1477-0520
Container-title:Organic & Biomolecular Chemistry
language:en
Short-container-title:Org. Biomol. Chem.

Author:

Bichovski Plamen¹²³⁴,Haas Thomas M.¹²³⁴,Keller Manfred¹²³⁴,Streuff Jan¹²³⁴

Affiliation:

1. Institut für Organische Chemie

2. Albert-Ludwigs-Universität Freiburg

3. 79104 Freiburg

4. Germany

Abstract

The title reaction leads to 1,6-difunctionalized products without the requirement of premetallated reagents. Details on scope, selectivity and mechanism are reported.

Funder

Verband der Chemischen Industrie

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/OB/C5OB02631H

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