Photocatalytic oxidation of Mn(<scp>ii</scp>) on the surface of Bi2.15WO6via the ligand-to-metal charge transfer (LMCT) pathway-Reference-Cited by-同舟云学术

Photocatalytic oxidation of Mn(ii) on the surface of Bi_2.15WO₆via the ligand-to-metal charge transfer (LMCT) pathway

Published:2022 Issue:19 Volume:24 Page:11527-11535
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Guo Xing-Fei¹,Liu Zhao-Yu¹,Ren Hai-Tao²,Yu Si-Yuan¹^ORCID,Han Xu³^ORCID

Affiliation:

1. State Key Laboratory of Hollow Fiber Membrane Materials and Processes, School of Environmental Science and Engineering, Tiangong University, Tianjin 300387, P. R. China

2. Innovation Platform of Intelligent and Energy-Saving Textiles, School of Textile Science and Engineering, Tiangong University, Tianjin 300387, P. R. China

3. School of Chemical Engineering and Technology, Tianjin University, Tianjin, P. R. China

Abstract

The formation of Mn(ii)–O–Bi(iii) complex (LMCT band) decreases the bandgap of Bi2.15WO6 and the photogenerated electrons are transferred from the LMCT band to the CB of Bi2.15WO6, accompanied by the oxidation of Mn(ii).

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CP/D2CP00623E

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