Thermal C–O coupling reactions of Ta methylene clusters [TanCH2]+ (n = 1, 4) with O2-Reference-Cited by-同舟云学术

Thermal C–O coupling reactions of Ta methylene clusters [TanCH2]+ (n = 1, 4) with O2

Published:2019 Issue:37 Volume:21 Page:20743-20749
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Masubuchi T.¹²³,Eckhard J. F.¹²³,Goddard G.¹²³,Tschurl M.¹²³^ORCID,Heiz U.¹²³^ORCID

Affiliation:

1. Lehrstuhl für Physikalische Chemie, Chemistry Department & Catalysis Research Center, Technische Universität München, Lichtenbergstr. 4

2. Garching

3. Germany

Abstract

Cationic tantalum carbenes [TaCH₂]⁺ and [Ta₄CH₂]⁺, products of methane dehydrogenation, are reacted with dioxygen in an ion trap. Detected products suggest a formation of value-added molecules originating from C–O coupling reactions.

Funder

Deutsche Forschungsgemeinschaft

Fondation CentraleSupélec

Deutscher Akademischer Austauschdienst

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C9CP02739D

Reference37 articles.

1. Methane activation on unsupported platinum clusters

2. Reaction Mechanisms for C−O Bond Coupling from Pt4CH2+ and O2: A Relativistic Density Functional Study

3. HCN synthesis from CH4 and NH3 on platinum*1

4. HCN synthesis from CH4, NH3, and O2 on clean Pt*1

5. Modeling catalytic gauze reactors: HCN synthesis

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