Reaction monitoring reveals poisoning mechanism of Pd2(dba)3 and guides catalyst selection-Reference-Cited by-同舟云学术

Reaction monitoring reveals poisoning mechanism of Pd2(dba)3 and guides catalyst selection

Published:2017 Issue:96 Volume:53 Page:12890-12893
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Colletto Chiara¹²³⁴^ORCID,Burés Jordi¹²³⁴^ORCID,Larrosa Igor¹²³⁴^ORCID

Affiliation:

1. School of Chemistry

2. The University of Manchester

3. Manchester

4. UK

Abstract

We have discovered that the dba ligand in the commonly used Pd₂(dba)₃·CHCl₃ cross-coupling pre-catalyst is susceptible to bis-arylation when used in the presence of aryl iodides.

Funder

Engineering and Physical Sciences Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC08018B

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