Synthesis and investigation into the structural, electronic and electrical properties of K2Pb(OCN)I3-Reference-Cited by-同舟云学术

Synthesis and investigation into the structural, electronic and electrical properties of K2Pb(OCN)I3

Published:2019 Issue:36 Volume:48 Page:13813-13819
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Siai Amira¹²³⁴⁵,Oprea Alexandru⁶⁴⁵,Ströbele Markus¹²³⁴⁵,Meyer Hans-Jürgen¹²³⁴⁵^ORCID

Affiliation:

1. Section for Solid State and Theoretical Inorganic Chemistry

2. Institute of Inorganic Chemistry

3. University of Tübingen

4. 72076 Tübingen

5. Germany

6. Institute of Physical and Theoretical Chemistry

Abstract

The new compound K₂Pb(OCN)I₃ was synthesized by the solid-state reaction of PbI₂ and KOCN. Built-up form two interpenetrating tetrahedral-octahedral frameworks, it is a direct band-gap semiconductor (2.4 eV) with rather high dielectric constant.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02124H

Reference37 articles.

1. Structure and Thermal Properties of Lithium Cyanate

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3. 499. Lattice parameters and infrared spectra of some inorganic cyanates

4. Phase transition and thermal decomposition of silver isocyanate (AgNCO)

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