A hydrogen-bonded assembly of cucurbit[6]uril and [MoO2Cl2(H2O)2] with catalytic efficacy for the one-pot conversion of olefins to alkoxy products-Reference-Cited by-同舟云学术

A hydrogen-bonded assembly of cucurbit[6]uril and [MoO2Cl2(H2O)2] with catalytic efficacy for the one-pot conversion of olefins to alkoxy products

Published:2019 Issue:30 Volume:48 Page:11508-11519
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nogueira Lucie S.¹²³⁴⁵^ORCID,Antunes Margarida M.¹²³⁴⁵^ORCID,Gomes Ana C.¹²³⁴⁵^ORCID,Cunha-Silva Luís⁶⁷⁸⁹¹⁰^ORCID,Pillinger Martyn¹²³⁴⁵^ORCID,Lopes André D.¹¹¹²¹³¹⁴¹⁵^ORCID,Valente Anabela A.¹²³⁴⁵^ORCID,Gonçalves Isabel S.¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. CICECO – Aveiro Institute of Materials

3. University of Aveiro

4. Campus Universitário de Santiago

5. 3810-193 Aveiro

6. REQUIMTE/LAQV & Department of Chemistry and Biochemistry

7. Faculty of Sciences

8. University of Porto

9. 4169-007 Porto

10. Portugal

11. CCMar

12. and Department of Chemistry and Pharmacy

13. FCT

14. University of the Algarve

15. P-8005-039 Faro

Abstract

A supramolecular cucurbit[6]uril/Mo^VI hydrogen-bonded assembly displays dual-function (oxidation/acid) catalytic behavior for the one-pot conversion of olefins to alkoxy products.

Funder

Fundação para a Ciência e a Tecnologia

Ministério da Educação e Ciência

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT02127B

Reference56 articles.

1. Oxide halides of molybdenum and tungsten. I. Preparations

2. Application of molybdenum(VI) dichloride dioxide (MoO2Cl2) in organic transformations

3. High-valent oxo-molybdenum and oxo-rhenium complexes as efficient catalysts for X–H (X = Si, B, P and H) bond activation and for organic reductions

4. High Valent Oxo-molybdenum Complexes as Efficient Catalysts for C-X Bond Forming Reactions

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