Improving the molecular spin qubit performance in zirconium MOF composites by mechanochemical dilution and fullerene encapsulation

Author:

Vujević Lucija1,Karadeniz Bahar1ORCID,Cindro Nikola2ORCID,Krajnc Andraž3,Mali Gregor3ORCID,Mazaj Matjaž3ORCID,Avdoshenko Stanislav M.4,Popov Alexey A.4ORCID,Žilić Dijana1ORCID,Užarević Krunoslav1ORCID,Kveder Marina1

Affiliation:

1. Ruđer Bošković Institute, Bijenička cesta 54, 10000 Zagreb, Croatia

2. Department of Chemistry, University of Zagreb, 10000 Zagreb, Croatia

3. National Institute of Chemistry, Hajdrihova 19, SI-1001 Ljubljana, Slovenia

4. Leibniz IFW Dresden, Helmholtzstrasse 20, D-01069 Dresden, Germany

Abstract

Mechanochemical encapsulation of C60 fullerene leads to a change in selectivity in the topology outcome and a significant increase in coherence among spin-active centers embedded in a moderately porous zirconium PCN-223 porphyrinic framework.

Funder

Deutsche Forschungsgemeinschaft

Deutscher Akademischer Austauschdienst

Javna Agencija za Raziskovalno Dejavnost RS

European Social Fund

Hrvatska Zaklada za Znanost

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

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