Improving spin crossover characteristics in heteroleptic [Fe<sup>III</sup>(qsal-5-I)(qsal-5-OMe)]A complexes-Reference-Cited by-同舟云学术

Improving spin crossover characteristics in heteroleptic [Fe^III(qsal-5-I)(qsal-5-OMe)]A complexes

Published:2023 Issue:48 Volume:52 Page:18148-18157
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Díaz-Torres Raúl¹^ORCID,Gómez-Coca Silvia²^ORCID,Ruiz Eliseo²,Harding Phimphaka³^ORCID,Harding David J.³^ORCID

Affiliation:

1. Thammasat University Research Unit in Multifunctional Crystalline Materials and Applications (TU-MCMA), Faculty of Science and Technology, Thammasat University, Pathum Thani 12121, Thailand

2. Departament de Química Inorgànica i Orgànica, Institut de Recerca de Química Teòrica i Computacional, Universitat de Barcelona, Diagonal 645, 08028 Barcelona, Spain

3. School of Chemistry, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima, 30000, Thailand

Abstract

Heteroleptic iron(iii) spin crossover complexes are reported with one of the compounds exhibiting a strongly hysteretic spin crossover that is superior to the homoleptic complexes.

Funder

National Research Council of Thailand

Ministerio de Ciencia e Innovación

Generalitat de Catalunya

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02503A

Reference56 articles.

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3. J.-F.Létard , P.Guionneau and L.Goux-Capes , in Spin Crossover in Transition Metal Compounds III , Springer-Verlag , Berlin/Heidelberg , 2004 , pp. 221–249

4. M. A.Halcrow , Spin-Crossover Materials , John Wiley & Sons Ltd , Oxford, UK , 2013 , pp. 147–169

5. Direct Observation of Ordered High-Spin-Low-Spin Intermediate States of an Iron(III) Three-Step Spin-Crossover Complex

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