Atomic-scale identification of Pd leaching in nanoparticle catalyzed C–C coupling: effects of particle surface disorder-Reference-Cited by-同舟云学术

Atomic-scale identification of Pd leaching in nanoparticle catalyzed C–C coupling: effects of particle surface disorder

Published:2015 Issue:11 Volume:6 Page:6413-6419
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Briggs Beverly D.¹²³⁴,Bedford Nicholas M.⁵⁶⁴¹²,Seifert Soenke⁷⁸⁹⁴,Koerner Hilmar⁵⁶⁴,Ramezani-Dakhel Hadi¹⁰¹¹¹²⁴,Heinz Hendrik¹⁰¹¹¹²⁴,Naik Rajesh R.⁵⁶⁴,Frenkel Anatoly I.¹³¹⁴¹⁵⁴,Knecht Marc R.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Miami

3. Coral Gables

4. USA

5. Materials and Manufacturing Directorate

6. Air Force Research Laboratory

7. X-Ray Science Division

8. Argonne National Laboratory

9. Argonne

10. Department of Polymer Engineering

11. University of Akron

12. Akron

13. Department of Physics

14. Yeshiva University

15. New York

Abstract

Atomically-resolved X-ray-based methods demonstrate that Pd atoms are leached via oxidative addition during nanoparticle-catalyzed Stille coupling under ambient reaction conditions.

Funder

National Science Foundation

Air Force Office of Scientific Research

Basic Energy Sciences

University of Miami

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01424G