Charge density distribution and theoretical analysis of low and high energy phosphate esters-Reference-Cited by-同舟云学术

Charge density distribution and theoretical analysis of low and high energy phosphate esters

Published:2015 Issue:117 Volume:5 Page:96623-96638
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Mermer Adrian¹²³⁴,Lis Tadeusz¹²³⁴,Starynowicz Przemysław¹²³⁴

Affiliation:

1. Wydział Chemii

2. Uniwersytet Wrocławski

3. 50-383 Wrocław

4. Poland

Abstract

There is a strict relation between the energy of hydrolysis of phosphate esters and the extent of interactions between the p ester oxygen lone pair and the antibonding orbitals of the rest of the molecule. Its impact on experimental charge density distribution is analyzed.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA12605C

Reference64 articles.

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2. Anomeric Effect in “High Energy” Phosphate Bonds. Selective Destabilization of the Scissile Bond and Modulation of the Exothermicity of Hydrolysis

3. Enzyme-Catalyzed Phosphoryl Transfer Reactions

4. Why Nature Chose Phosphates

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