Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center-Reference-Cited by-同舟云学术

Efficient and selective alkene hydrosilation promoted by weak, double Si–H activation at an iron center

Published:2020 Issue:27 Volume:11 Page:7070-7075
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Smith Patrick W.¹²³⁴^ORCID,Dong Yuyang¹²³⁴^ORCID,Tilley T. Don¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of California, Berkeley

3. Berkeley

4. USA

Abstract

Cationic iron complexes [Cp*(ⁱPr₂MeP)FeH₂SiHR]⁺, generated and characterized in solution, are very efficient catalysts for the hydrosilation of terminal alkenes and internal alkynes by primary silanes at low catalyst loading (0.1 mol%) and ambient temperature.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC01749C

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