Lewis acid-assisted Ir(iii) reductive elimination enables construction of seven-membered-ring sulfoxides

Author:

Yang Wu12345,Li Yingzi12345,Zhu Jiefeng12345,Liu Wentan12345,Ke Jie12345,He Chuan12345ORCID

Affiliation:

1. Shenzhen Grubbs Institute

2. Department of Chemistry

3. Guangdong Provincial Key Laboratory of Catalysis

4. Southern University of Science and Technology

5. Shenzhen 518055

Abstract

With a rationally designed Lewis acid assisted oxidatively induced strategy, the sluggish Ir(III) reductive elimination is successfully facilitated, which enables the facile construction of versatile seven-membered-ring sulfoxides.

Funder

Southern University of Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Reference59 articles.

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