Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni(ii)-Reference-Cited by-同舟云学术

Covalent attachment of diphosphine ligands to glassy carbon electrodes via Cu-catalyzed alkyne-azide cycloaddition. Metallation with Ni(ii)

Published:2015 Issue:27 Volume:44 Page:12225-12233
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Das Atanu K.¹²³⁴⁵,Engelhard Mark H.⁶³⁴⁵,Lense Sheri¹²³⁴⁵,Roberts John A. S.¹²³⁴⁵,Bullock R. Morris¹²³⁴⁵

Affiliation:

1. Center for Molecular Electrocatalysis

2. Physical Sciences Division

3. Pacific Northwest National Laboratory

4. Richland

5. USA

6. Environmental Molecular Sciences Laboratory

Abstract

Covalent tethering of a P₂N₂ ligand to a planar, azide-terminated glassy carbon electrode surface was accomplished using a Cu^I-catalyzed “click” reaction, followed by metallation with Ni^II.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00162E

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