Aerobic oxygenation catalyzed by first row transition metal complexes coordinated by tetradentate mono-carbon bridged bis-phenanthroline ligands: intra- versus intermolecular carbon–hydrogen bond activation
Author:
Affiliation:
1. Department of Organic Chemistry
2. Weizmann Institute of Science
3. Rehovot
4. Israel 76100
5. Department of Chemical Research Support
Abstract
Intra- and intermolecular aerobic oxygenation is initiated by activation of carbon–hydrogen bonds and/or O2 and propagated by an autoxidation pathway.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00828D
Reference51 articles.
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2. Introduction: Oxygen Reduction and Activation in Catalysis
3. Oxygen Activation and Radical Transformations in Heme Proteins and Metalloporphyrins
4. Dioxygen Activation by Nonheme Diiron Enzymes: Diverse Dioxygen Adducts, High-Valent Intermediates, and Related Model Complexes
5. Copper-Promoted Functionalization of Organic Molecules: from Biologically Relevant Cu/O2Model Systems to Organometallic Transformations
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