Tailoring the d-band center of porous CoS<sub>2</sub> nanospheres <i>via</i> low-electronegative Fe for weakened OH* adsorption and boosted oxygen evolution-Reference-Cited by-同舟云学术

Tailoring the d-band center of porous CoS₂ nanospheres via low-electronegative Fe for weakened OH* adsorption and boosted oxygen evolution

Published:2023 Issue:19 Volume:10 Page:5668-5677
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Chen Heyuan¹,Wu Wei¹,Chen Suhao¹,Wang Zichen¹,Chen Runzhe¹,Cheng Niancai¹²^ORCID

Affiliation:

1. College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, Fujian, China

2. Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin 300071, China

Abstract

The doping of low-electronegative Fe changes the charge distribution of Co sites as well as downshifts the d-band center of Co sites to reduce the binding barrier between Co sites and *OH.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QI/D3QI00902E

Reference66 articles.

1. Electronic Structure Modulation of Nanoporous Cobalt Phosphide by Carbon Doping for Alkaline Hydrogen Evolution Reaction

2. Optimizing the Oxygen‐Catalytic Performance of Zn–Mn–Co Spinel by Regulating the Bond Competition at Octahedral Sites

3. Activating Lattice Oxygen in Spinel Oxides via Engineering Octahedral Sites for Oxygen Evolution

4. Thiacalixarene-based {Co/Fe}₁₆ coordination clusters: bimetallic synergistic effect for an enhanced oxygen evolution reaction

5. p–d hybridization in CoFe LDH nanoflowers for efficient oxygen evolution electrocatalysis

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