TICT compounds by design: comparison of two naphthalimide-π-dimethylaniline conjugates of different lengths and ground state geometries

Author:

Jovaišaitė Justina1ORCID,Baronas Paulius1ORCID,Jonusauskas Gediminas2ORCID,Gudeika Dalius3ORCID,Gruodis Alytis4,Gražulevičius Juozas V.3ORCID,Juršėnas Saulius1

Affiliation:

1. Institute of Photonics and Nanotechnology, Vilnius University, Saulėtekio Ave. 3, LT-10257 Vilnius, Lithuania

2. Laboratoire Ondes et Matiére d’Aquitaine, Bordeaux University, UMR CNRS 5798, 351 cours de la Libération, 33405 Talence, France

3. Department of Polymer Chemistry and Technology, Kaunas University of Technology, Radvilėnų rd. 19, LT-50254 Kaunas, Lithuania

4. Institute of Chemical Physics, Vilnius University, Saulėtekio Ave. 3, LT-10257 Vilnius, Lithuania

Abstract

Two new naphthalimide-π-dimethylaniline derivatives possess twisted charge transfer (TICT) excited states with reaction rates outcompeting dynamic solvation.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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