Spontaneous and induced chiral symmetry breaking of stereolabile pillar[5]arene derivatives upon crystallisation-Reference-Cited by-同舟云学术

Spontaneous and induced chiral symmetry breaking of stereolabile pillar[5]arene derivatives upon crystallisation

Published:2021 Issue:33 Volume:12 Page:10985-10989
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Haiying¹^ORCID,Yang Weiwei¹^ORCID,Baldridge Kim K.¹^ORCID,Zhan Cai-Hong²^ORCID,Thikekar Tushar Ulhas¹³^ORCID,Sue Andrew C.-H.³^ORCID

Affiliation:

1. School of Pharmaceutical Science & Technology, Tianjin University, 92 Weijin Road, Nankai District, Tianjin 300072, P. R. China

2. College of Chemistry and Life Sciences, Zhejiang Normal University, 688 Yingbin Road, Jinhua, Zhejiang Province 321004, P. R. China

3. College of Chemistry and Chemical Engineering, Xiamen University, 422 Siming S Rd, Siming District, Xiamen, Fujian Province 361005, P. R. China

Abstract

Stereolabile pillar[5]arene derivatives, which are dynamic racemic mixtures in solution on account of their low inversion barriers, were employed as platforms to study chiral symmetry breaking during crystallisation.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02560K

Reference53 articles.

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2. Louis Pasteur's discovery of molecular chirality and spontaneous resolution in 1848, together with a complete review of his crystallographic and chemical work

3. The resolution of racemic acid: A classic stereochemical experiment for the undergraduate laboratory

4. The reexamination of Pasteur's experiment in Japan

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