N-doped semi-graphitic C loaded with metallic Co: synthesis parameters and catalytic selective reduction of p-nitrophenol

Author:

Zhang Qinjun1,Lu Xinhuan1,Yue Fanfan1,Guo Haotian1,Shi Congxing1,Tao Yiyuan1,Duan Jingui2ORCID,Zhou Dan1ORCID,Xia Qinghua1ORCID

Affiliation:

1. Collaborative Innovation Center for Advanced Organic Chemical Materials Co-constructed by the Province and Ministry, Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Ministry-of-Education Key Laboratory for Green Preparation and Application of Functional Materials, Hubei Provincial Engineering Center of Performance Chemicals, Hubei University, Wuhan 430062, P. R. China

2. State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, P. R. China

Abstract

The N-doped semi-graphitic C loaded with metallic Co (Co/CN) could catalyze highly selective hydrogenation of p-nitrophenol (100% conversion) to p-aminophenol (98.5% selectivity). The magnetically separable catalyst was reusable for 14 cycles.

Funder

National Natural Science Foundation of China

Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Ministry of Education

State Key Laboratory of Materials- Oriented Chemical Engineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

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