Discarding metal incorporation in pyrazole macrocycles and the role of the substrate on single-layer assemblies-Reference-Cited by-同舟云学术

Discarding metal incorporation in pyrazole macrocycles and the role of the substrate on single-layer assemblies

Published:2024 Issue:14 Volume:16 Page:7093-7101
ISSN:2040-3364
Container-title:Nanoscale
language:en
Short-container-title:Nanoscale

Author:

Lobo-Checa Jorge¹²³^ORCID,Rodríguez Sindy Julieth⁴^ORCID,Hernández-López Leyre¹²,Herrer Lucía¹³,Passeggi Mario C. G.⁴⁵^ORCID,Cea Pilar¹³⁶^ORCID,Serrano José Luis¹⁷^ORCID

Affiliation:

1. Instituto de Nanociencia y Materiales de Aragón (INMA), CSIC-Universidad de Zaragoza, Zaragoza 50009, Spain

2. Departamento de Física de la Materia Condensada, Universidad de Zaragoza, E-50009 Zaragoza, Spain

3. Laboratorio de Microscopias Avanzadas, Universidad de Zaragoza, E-50018, Zaragoza, Spain

4. Instituto de Física del Litoral, Consejo Nacional de Investigaciones Científicas y Técnicas y Universidad Nacional del Litoral (IFIS-Litoral, CONICET-UNL), Santa Fe, Argentina

5. Departamento de Física, Facultad de Ingeniería Química, Universidad Nacional del Litoral, Santa Fe, Argentina

6. Departamento de Química Física, Facultad de Ciencias, Universidad de Zaragoza, E-50009 Zaragoza, Spain

7. Departamento de Química Orgánica, Facultad de Ciencias, Universidad de Zaragoza, E-50009 Zaragoza, Spain

Abstract

Metal adatoms do not split, nor replace, the hydrogens at the coordination nodes of pyrazole derivates when forming metallophilic complexes on surfaces. The porous structures are driven by kinetics into divergent substrate dependent arrangements.

Funder

Ministerio de Economía y Competitividad

Ministerio de Ciencia e Innovación

Agencia Estatal de Investigación

European Regional Development Fund

European Commission

Departamento de Educación, Cultura y Deporte, Gobierno de Aragón

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NR/D3NR03773H

Reference50 articles.

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4. Efficient and Environmentally Friendly Adsorbent Based on β-Ketoenol-Pyrazole-Thiophene for Heavy-Metal Ion Removal from Aquatic Medium: A Combined Experimental and Theoretical Study

5. Recent progress in chemosensors based on pyrazole derivatives