Unprecedented pseudo-zeroth-order kinetics of the catecholase-like activity of mixed-valence MnIIMn2III complexes-Reference-Cited by-同舟云学术

Unprecedented pseudo-zeroth-order kinetics of the catecholase-like activity of mixed-valence Mn^IIMn₂^III complexes

Published:2023 Issue:20 Volume:47 Page:9681-9691
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Dasgupta Sanchari¹²,Karim Suhana¹,Khatua Somanjana³,Adhikary Amit¹^ORCID,Acharya Krishnendu³^ORCID,Zangrando Ennio⁴^ORCID,Maity Suvendu⁵,Das Debasis¹^ORCID

Affiliation:

1. Department of Chemistry, University of Calcutta, 92, A. P. C. Road, Kolkata 700009, India

2. Institut Lavoisier de Versailles, UMR CNRS 8180, Universite de Versailles St-Quentin-en-Yvelines, Universite Paris-Saclay, 78035 Versailles Cedex, France

3. Molecular and Applied Mycology and Plant Pathology Laboratory, Centre of Advanced Study, Department of Botany, University of Calcutta, 35, Ballygunge Circular Road, Kolkata, 700019, India

4. Department of Chemical and Pharmaceutical Sciences, University of Trieste, Via L. Giorgieri 1, 34127 Trieste, Italy

5. Department of Chemistry, R. K. Mission Residential College, Narendrapur, Kolkata 700103, India

Abstract

The pseudo-zero-order kinetics of the catecholase-like activity of biologically active linear trinuclear mixed-valence manganese complexes have been explored; the formation of singlet oxygen is thought to be the rate-limiting step.

Funder

Department of Science and Technology, Ministry of Science and Technology, India

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D2NJ06357C

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