Synthesis of methylal from methanol and formaldehyde catalyzed by Brønsted acid ionic liquids with different alkyl groups
Author:
Affiliation:
1. Beijing Key Laboratory for Chemical Power Source and Green Catalysis
2. School of Chemical Engineering and the Environment
3. Beijing Institute of Technology
4. Beijing 100081
5. China
Abstract
The carbon chain length of ILs has an effect on its catalytic activity. The ionic liquid of [C6ImBS][HSO4] shows the best catalytic performance which is near that of concentrated sulfuric acid and p-toluene sulfonic acid.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/RA/C5RA18598J
Reference29 articles.
1. NIST, http://webbook.nist.gov/cgi/cbook.cgi?Name=methylal+&Units=SI&cTG=on&cTC=on&cTP=on&cTR=on&cIE=on&cIC=on, (accessed September 2015)
2. Purification and dehydration of methylal by pervaporation
3. Fuel design concept for improving the spray characteristics and emissions of diesel engines
4. Ultra-low-emission diesel engine fuelled with dimethoxymethane—diesel fuel blends
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