Characterization of selenium in UO2spent nuclear fuel by micro X-ray absorption spectroscopy and its thermodynamic stability

Author:

Curti E.12,Puranen A.345,Grolimund D.12,Jädernas D.345,Sheptyakov D.12,Mesbah A.678910

Affiliation:

1. Paul Scherrer Institut

2. Switzerland

3. Studsvik Nuclear AB

4. Nyköping

5. Sweden

6. Department of Chemistry

7. Northwestern University

8. Evanston

9. USA

10. ICSM UMR 5257 CNRS/CEA/UM2/ENCSM

Abstract

The long-lived fission product79Se is tightly bound to the UO2lattice in spent nuclear fuel; it will thus be released only very slowly from a geological repository for radioactive waste.

Funder

European Commission

Publisher

Royal Society of Chemistry (RSC)

Subject

Management, Monitoring, Policy and Law,Public Health, Environmental and Occupational Health,Environmental Chemistry,General Medicine

Reference30 articles.

1. P. A. Witherspoon and G. S.Bodvarsson, Geological Challange in Radioactive Waste Isolation, Lawrence Berkeley National Laboratory, Berkeley, 2006

2. L. O. Werme , L. H.Johnson, V. M.Oversby, F.King, K.Spahiu, B.Grambow and D. W.Shoesmith, Technical report TR-04-19, Svensk Kärnbränslehantering AB (SKB), Stockholm, Sweden, 2004

3. Spent fuel radionuclide source-term model for assessing spent fuel performance in geological disposal. Part I: Assessment of the instant release fraction

4. Spent fuel radionuclide source term model for assessing spent fuel performance in geological disposal. Part II: Matrix alteration model and global performance

5. Radiation Induced Spent Nuclear Fuel Dissolution under Deep Repository Conditions

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