Synthesis and unique reversible splitting of 14-membered cyclic aminomethylphosphines on to 7-membered heterocycles

Author:

Musina Elvira I.123,Fesenko Tatiana I.123,Strelnik Igor D.123,Polyancev Fedor M.123,Latypov Shamil K.123,Lönnecke Peter4567,Hey-Hawkins Evamarie4567,Karasik Andrey A.123,Sinyashin Oleg G.123

Affiliation:

1. A.E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS

2. Kazan

3. Russian Federation

4. Institute of Inorganic Chemistry

5. Leipzig University

6. 04103 Leipzig

7. Germany

Abstract

Unique reversible process of novel 14-membered cyclic polyphosphines splitting onto rac- and meso- stereoisomers of 1-aza-3,6-diphosphacycloheptanes has been discovered.

Funder

Russian Foundation for Basic Research

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference40 articles.

1. A. A. Karasik and O. G.Sinyashin, in Phosphorus Compounds Advanced Tools in Catalysis and Material Sciences, ed. M. Peruzzini and L. Gonsalvi, Springer, Netherlands, 2011, ch. 37, vol. 12, pp. 375–444

2. Synthesis of Phosphorus-Containing Macrocycles and Cryptands

3. Phosphorus macrocycles and cryptands

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