Synthesis and unique reversible splitting of 14-membered cyclic aminomethylphosphines on to 7-membered heterocycles
Author:
Affiliation:
1. A.E. Arbuzov Institute of Organic and Physical Chemistry of KSC RAS
2. Kazan
3. Russian Federation
4. Institute of Inorganic Chemistry
5. Leipzig University
6. 04103 Leipzig
7. Germany
Abstract
Unique reversible process of novel 14-membered cyclic polyphosphines splitting onto rac- and meso- stereoisomers of 1-aza-3,6-diphosphacycloheptanes has been discovered.
Funder
Russian Foundation for Basic Research
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT01910A
Reference40 articles.
1. A. A. Karasik and O. G.Sinyashin, in Phosphorus Compounds Advanced Tools in Catalysis and Material Sciences, ed. M. Peruzzini and L. Gonsalvi, Springer, Netherlands, 2011, ch. 37, vol. 12, pp. 375–444
2. Synthesis of Phosphorus-Containing Macrocycles and Cryptands
3. Phosphorus macrocycles and cryptands
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