A microporous metal–organic framework with polarized trifluoromethyl groups for high methane storage

Author:

Chang Ganggang12345,Li Bin1234,Wang Hailong1234,Bao Zongbi12345,Yildirim Taner67849,Yao Zizhu1011121314,Xiang Shengchang1011121314,Zhou Wei6784,Chen Banglin1234

Affiliation:

1. Department of Chemistry

2. University of Texas at San Antonio

3. San Antonio

4. USA

5. Key Laboratory of Biomass Chemical Engineering of Ministry of Education

6. NIST Center for Neutron Research

7. National Institute of Standards and Technology

8. Gaithersburg

9. Department of Materials Science and Engineering

10. College of Material Science and Engineering

11. Fujian Provincial Key Laboratory of Polymer Materials

12. Fujian Normal University

13. Fuzhou 350007

14. China

Abstract

A novel NbO-type metal–organic framework UTSA-88a with polarized trifluoromethyl groups exhibits a notably high methane storage capacity of 248 cm3 (STP) cm−3 and a working capacity of 185 cm3 (STP) cm−3.

Funder

Welch Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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