Charge compensation in a layered van der Waals NiPS3 host through various cationic intercalations

Author:

Pazek Sebastian1,Efimenko Anna2,Félix Roberto2ORCID,Roslova Maria1,Querebillo Christine Joy1ORCID,Gorbunov Mikhail V.1ORCID,Ovchinnikov Alexander3ORCID,Koitzsch Andreas1ORCID,Escudero Carlos4ORCID,Shemerliuk Yuliia1,Aswartham Saicharan1,Büchner Bernd1,Omar Ahmad1,Mikhailova Daria1ORCID

Affiliation:

1. Leibniz Institute for Solid State and Materials Research (IFW), Dresden e.V. Helmholtzstr. 20, 01069 Dresden, Germany

2. Department Interface Design, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH (HZB), Albert-Einstein-Str. 15, 12489 Berlin, Germany

3. Department of Chemistry and Food Chemistry, Technische Universität Dresden, 01062 Dresden, Germany

4. ALBA Synchrotron, Carrer de la Llum 2-26, 08290 Cerdanyola del Vallès, Barcelona, Spain

Abstract

Electrochemical cation intercalation into 2D NiPS3 leads either to reduction of the (P2S6)4− units (Li example) or Ni cations (Na example), or causes electrochemical reduction and decomposition of EMIM cations within the van der Waals interlayers.

Funder

Deutsche Forschungsgemeinschaft

Bundesministerium für Bildung und Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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