(Et4N)[MoIII(DAPBH)Cl2], the first pentagonal-bipyramidal Mo(iii) complex with a N3O2-type Schiff-base ligand: manifestation of unquenched orbital momentum and Ising-type magnetic anisotropy-Reference-Cited by-同舟云学术

(Et4N)[MoIII(DAPBH)Cl2], the first pentagonal-bipyramidal Mo(iii) complex with a N3O2-type Schiff-base ligand: manifestation of unquenched orbital momentum and Ising-type magnetic anisotropy

Published:2018 Issue:72 Volume:54 Page:10084-10087
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Manakin Yu. V.¹²³⁴^ORCID,Mironov V. S.¹²³⁴⁵^ORCID,Bazhenova T. A.¹²³⁴,Lyssenko K. A.⁶⁷⁸⁴,Gilmutdinov I. F.⁹¹⁰¹¹⁴^ORCID,Bikbaev K. Sh.¹²³⁴,Masitov A. A.¹²³⁴,Yagubskii E. B.¹²³⁴

Affiliation:

1. Institute of Problems of Chemical Physics

2. IPCP RAS

3. Chernogolovka

4. Russia

5. Shubnikov Institute of Crystallography of Federal Scientific Research Centre “Crystallography and Photonics” RAS

6. A. N. Nesmeyanov Institute of Organoelement Compounds

7. RAS

8. Moscow

9. Institute of Physics

10. Kazan Federal University

11. Kazan

Abstract

We demonstrate that a planar pentadentate organic ligand can generate sufficiently strong ligand-field to stabilize the low-spin orbitally-degenerate configuration of Mo(iii) that results in strong Ising-type magnetic anisotropy.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CC/C8CC06038J

Reference35 articles.

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3. Molecular nanomagnets for information technologies

4. Molecular spins for quantum information technologies

5. On Approaching the Limit of Molecular Magnetic Anisotropy: A Near-Perfect Pentagonal Bipyramidal Dysprosium(III) Single-Molecule Magnet

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