Selective oxidation passing through η3-ozone intermediates: applications to direct propene epoxidation using molecular oxygen oxidant-Reference-Cited by-同舟云学术

Selective oxidation passing through η3-ozone intermediates: applications to direct propene epoxidation using molecular oxygen oxidant

Published:2014 Issue:53 Volume:4 Page:27755-27774
ISSN:2046-2069
Container-title:RSC Adv.
language:en
Short-container-title:RSC Adv.

Author:

Manz Thomas A.¹²³,Yang Bo¹²³

Affiliation:

1. Chemical Engineering Department

2. New Mexico State University

3. Las Cruces, USA

Abstract

An unprecedented catalytic route for selective oxidation is designed that passes through η³-ozone intermediates and uses molecular oxygen as the oxidant without requiring a coreductant. DFT-computed reaction cycles identify a new catalyst type with the lowest computed overall activation energy for direct propene epoxidation for any catalyst to date.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/RA/C4RA03729D

Reference64 articles.

1. Production of Top 50 Chemicals Increased Substantially in 1994

2. D. Kahlich , U.Wiechern and J.Linder, in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co. KGaA, 2012, vol. 30, pp. 313–335

3. The properties of unsaturated polyester based on the glycolyzed poly(ethylene terephthalate) with various glycol compositions

4. Industrial application of ionic liquids as process aid

5. Aircraft de-icer: Recycling can cut carbon emissions in half

Cited by 14 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Electronic Structure and CO₂ Reactivity of Group IV/V/VI Tetraperoxometalates;The Journal of Physical Chemistry A;2024-09-04

2. Implementing vanadium peroxides as direct air carbon capture materials;Chemical Science;2024

3. Metallic electrical contact materials: DFT calculations, wetting mechanism and arc resistance;Materials Today Physics;2024-01

4. Critical Role of Chlorinated Hydrocarbons in Propylene Epoxidation over K-Ag/CaCO₃;ACS Catalysis;2023-05-22

5. Supramolecular architectures of mononuclear nickel(II) and homobinuclear copper(II) complexes with the 5,5′-dimethyl-2,2′-bipyridine ligand: Syntheses, crystal structures and Hirshfeld surface analyses;Journal of Molecular Structure;2022-02