Unexpected formation of 4,4-dimethyl-1,2-disubstituted-dicarbonyl cyclopentanes from ketone enolate anions and 1,3-diiodo-2,2-dimethylpropane
Author:
Affiliation:
1. INFIQC-CONICET
2. Dpto. de Química Orgánica
3. Facultad de Ciencias Químicas
4. Universidad Nacional de Córdoba
5. Ciudad Universitaria
Abstract
Novel access to 1,2-dicarbonyl cyclopentane compounds by tandem dimerization–cyclization reactions under transition-metal-free conditions.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,General Chemistry,Catalysis
Link
http://pubs.rsc.org/en/content/articlepdf/2016/NJ/C5NJ03672K
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1. Novel hybrid-pyrrole derivatives: their synthesis, antitubercular evaluation and docking studies
2. One-pot metal-free synthesis of highly substituted pyrroles from 2-acetyl-3-methylene-1,4-dicarbonyl compounds and primary amines via TBHP and activated carbon oxidative aromatization of dihydropyrrole
3. Intermediates in the Paal-Knorr synthesis of pyrroles
4. A New Facile Approach to the Synthesis of 3-Methylthio-Substituted Furans, Pyrroles, Thiophenes, and Related Derivatives
5. A simple enantioselective preparation of (2S,5S)-2,5-diphenylpyrrolidine and related diaryl amines
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1. ChemInform Abstract: Unexpected Formation of 4,4-Dimethyl-1,2-disubstituted-dicarbonyl Cyclopentanes from Ketone Enolate Anions and 1,3-Diiodo-2,2-dimethylpropane.;ChemInform;2016-09
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