Hydrogen sulfide gas capture by organic superbase 1,8-diazabicyclo-[5.4.0]-undec-7-ene through salt formation: salt synthesis, characterization and application for CO2capture
Author:
Affiliation:
1. Technical Chemistry
2. Department of Chemistry
3. Chemical-Biological Centre
4. Umeå University
5. SE-90187 Umeå
Abstract
The organic superbase DBU captured H2S gas by protonation of one of its nitrogen atoms where a liquid, colorless, molecular DBU turned to solid greenish salt, [DBU][SH].
Funder
Vetenskapsrådet
Kempestiftelserna
Knut och Alice Wallenbergs Stiftelse
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA02993H
Reference40 articles.
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3. United States Department of Labor, Occupational Safety and Health Administration. Hydrogen Sulfide, Hazards, https://www.osha.gov/SLTC/hydrogensulfide/hazards.html
4. Synthesis of metal-oxide pillared montmorillonite clay for the selective catalytic oxidation of H2S
5. Kinetic study of hydrogen sulfide absorption in aqueous chlorine solution
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