The dual behaviour of β-vinylporphyrins in the presence of α,α′-dioxothiones-Reference-Cited by-同舟云学术

The dual behaviour of β-vinylporphyrins in the presence of α,α′-dioxothiones

Published:2023 Issue:44 Volume:47 Page:20266-20271
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Dias Cristina J.¹²^ORCID,Papi Francesco³^ORCID,Denis Maxime³⁴,Nativi Cristina³^ORCID,Neves M. Graça P. M. S.¹^ORCID,Faustino M. Amparo F.¹^ORCID

Affiliation:

1. LAQV-Requimte and Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal

2. iBiMED – Institute of Biomedicine, Department of Medical Sciences, University of Aveiro, 3810-193 Aveiro, Portugal

3. Department of Chemistry, University of Florence, via della Lastruccia, 3-13, I-50119 Sesto F.no (FI), Italy

4. Giotto Biotech, via L. Sacconi, 6, Sesto Fiorentino (FI), Italy

Abstract

α,α′-Dioxothione react with meso-tetraarylporphyrins bearing vinyl functionalities as a heterodienophiles or as a heterodienes. The dual behaviour is dependent on the absence or on the presence of a metal ion on the porphyrin inner core.

Funder

Fundação para a Ciência e a Tecnologia

European Cooperation in Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2023/NJ/D3NJ02859C

Reference27 articles.

1. Phthalimidosulfenyl chloride. Part 5. Reaction with enolizable carbonyl compounds and synthesis of functionalized thiones.

2. Phthalimidesulfenyl Chloride. 9. A Simple Access to .alpha.,.alpha.'-Dioxothiones, a New Class of Bis-heterodienes. Synthesis of 1,4-Oxathiin Systems

3. Phthalimidesulfenyl Chloride.1 11. Generation, General Reactivity, and Synthetic Applications of o-Thioquinones

4. Hetero Diels–Alder reactions (HDAR) of α,α′-dioxothiones on solid support

5. α-oxosulfines part 2: The first example of Ortho-thioquinone-S-oxides