Site-dependent effects of methylation on the electronic spectra of jet-cooled methylated xanthine compounds
Author:
Affiliation:
1. Department of Chemistry
2. Seoul National University
3. Seoul 08826
4. Korea
5. Kookmin University
6. Seoul 02703
7. Chungbuk National University
8. Chungbuk 28644
Abstract
The torsional barrier of methylated xanthine compounds is affected by a methyl-adjacent carbonyl or methyl group in the ground state, whereas it is governed in the excited state by the hyperconjugation interaction in the LUMO.
Funder
National Research Foundation of Korea
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2017/CP/C7CP03380J
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