Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes-Reference-Cited by-同舟云学术

Ni-catalyzed migratory fluoro-alkenylation of unactivated alkyl bromides with gem-difluoroalkenes

Published:2019 Issue:4 Volume:10 Page:1144-1149
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Zhou Lu¹²³⁴⁵,Zhu Chuan¹²³⁴⁵,Bi Peijia¹²³⁴⁵,Feng Chao¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Advanced Synthesis

2. School of Chemistry and Molecular Engineering

3. Jiangsu National Synergetic Innovation Center for Advanced Materials

4. Nanjing Tech University

5. Nanjing 211816

Abstract

A migratory fluoro-alkenylation of unactivated alkyl bromides is reported; the reaction is enabled by fluorine effects and involves an alkyl nickel chain-walking mechanism.

Funder

Natural Science Foundation of Jiangsu Province

Nanjing Tech University

Recruitment Program of Global Experts

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC04162H

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