Highly selective adsorption of ethylene over ethane in a MOF featuring the combination of open metal site and π-complexation

Author:

Zhang Yiming1234,Li Baiyan12345,Krishna Rajamani6789,Wu Zili10114,Ma Dingxuan512131415,Shi Zhan512131415,Pham Tony1234,Forrest Katherine1234,Space Brian1234,Ma Shengqian1234

Affiliation:

1. Department of Chemistry

2. University of South Florida

3. Tampa

4. USA

5. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry

6. Van't Hoff Institute for Molecular Sciences

7. University of Amsterdam

8. 1098 XH Amsterdam

9. Netherlands

10. Center for Nanophase Materials Science and Chemical Science Division

11. Oak Ridge National Laboratory

12. College of Chemistry

13. Jilin University

14. Changchun 130012

15. People's Republic of China

Abstract

A MOF featuring the combination of open metal site and π-complexation demonstrates exceptional ethylene–ethane adsorption selectivity at 318 K.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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