Synthesis of ultrahigh molecular weight polymers by homopolymerisation of higher α-olefins catalysed by aryloxo-modified half-titanocenes-Reference-Cited by-同舟云学术

Synthesis of ultrahigh molecular weight polymers by homopolymerisation of higher α-olefins catalysed by aryloxo-modified half-titanocenes

Published:2016 Issue:20 Volume:6 Page:16203-16207
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Nomura Kotohiro¹²³⁴⁵,Pengoubol Sarntamon¹²³⁴⁵,Apisuk Wannida¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Graduate School of Science and Engineering

3. Tokyo Metropolitan University

4. Hachioji

5. Japan

Abstract

Polymerisations of 1-dodecene, 1-hexadecene, 1-octadecene by Cp*TiX₂(O-2,6-ⁱPr₂C₆H₃) – cocatalysts afforded (ultra)high molecular weight polymers with unimodal molecular weight distributions.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA27797C

Reference59 articles.

1. The Search for New-Generation Olefin Polymerization Catalysts: Life beyond Metallocenes

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