Oxidant speciation and anionic ligand effects in the gold-catalyzed oxidative coupling of arenes and alkynes-Reference-Cited by-同舟云学术

Oxidant speciation and anionic ligand effects in the gold-catalyzed oxidative coupling of arenes and alkynes

Published:2019 Issue:36 Volume:10 Page:8411-8420
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Hofer Manuel¹²³⁴,de Haro Teresa¹²³⁴,Gómez-Bengoa Enrique⁵⁶⁷⁸^ORCID,Genoux Alexandre¹²³⁴,Nevado Cristina¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Zürich

3. Zürich

4. Switzerland

5. Departamento de Química Orgánica I

6. Universidad del Pais Vasco

7. CP-20080 Donostia-San Sebastián

8. Spain

Abstract

The mechanism of the gold-catalyzed oxidative cross-coupling of arenes and alkynes has been studied in detail combining stoichiometric experiments with putative reaction intermediates and DFT calculations.

Funder

H2020 European Research Council

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC02372K

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