Quantum fluctuations of a fullerene cage modulate its internal magnetic environment

Author:

Kawatsu Tsutomu1234ORCID,Tachikawa Masanori1234

Affiliation:

1. Graduate School of Nanobioscience

2. Yokohama City University

3. Kanazawa-ku

4. Japan

Abstract

Quantum delocalization of the C60 HOMO–LUMO gap results in an upfield of nuclear magnetic shielding on an encapsulated hydrogen molecule.

Funder

Ministry of Education, Culture, Sports, Science and Technology

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference107 articles.

1. The Chemical Physics of fullerenes 10 (and 5) years later: Series E: Applied Sciences , ed. W. Andreoni , Kluwer Academic Publishers , Dordrecht , 1996

2. The physics of fullurene-based and fullerene-related materials , ed. W. Andreoni , Kluwer Academic Publishers , Dordrecht , 2000

3. Fullerenes: Chemistry, physics, and technology , ed. K. M. Kadish and R. S. Ruoff , John Wiley & Sons, Inc ., New York , 2000

4. Dynamic charge fluctuation of endohedral fullerene with coencapsulated Be atom and H2

5. The Spin Chemistry and Magnetic Resonance of H2@C60. From the Pauli Principle to Trapping a Long Lived Nuclear Excited Spin State inside a Buckyball

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