Distance-dependent formation of electronic charge-transfer states in the ground states of anthracene and pyrene covalently linked to a TEMPO free radical-Reference-Cited by-同舟云学术

Distance-dependent formation of electronic charge-transfer states in the ground states of anthracene and pyrene covalently linked to a TEMPO free radical

Published:2019 Issue:1 Volume:21 Page:77-88
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Tripathi Alok Kumar¹²³^ORCID,Kundu Sushma¹²³,Das Ranjan¹²³^ORCID

Affiliation:

1. Tata Institute of Fundamental Research

2. Mumbai 400005

3. India

Abstract

Charge-transfer states are shown in molecules consisting of a covalently linked anthracene or pyrene moiety (acceptor) and a TEMPO free radical (donor) through a spacer group of different lengths. Efficiency of the formation of CT states decreases exponentially with the distance separating the two moieties.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2019/CP/C8CP06722H

Reference15 articles.

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