Use of 15N NMR spectroscopy to probe covalency in a thorium nitride
Author:
Affiliation:
1. Department of Chemistry and Biochemistry
2. University of California
3. Santa Barbara
4. USA
5. Department of Chemistry
6. University at Buffalo
7. State University of New York
8. Buffalo
Abstract
The first isolable molecular thorium nitride, [(NR2)3Th(μ-N)Th(NR2)3]−, was synthesized by reaction of [Th{N(R)(SiMe2)CH2}(NR2)2] with NaNH2 and characterized by X-ray crystallography, 15N NMR spectroscopy, and DFT calculations.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C9SC01960J
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