The distribution of rare earth ions in a γ-Ga2O3 nanocrystal-silicate glass composite and its influence on the photoluminescence properties

Author:

Gao Zhigang12345ORCID,Lu Xiaosong12345,Chu Yushi12345,Guo Shu6745,Liu Lu12345,Liu Yinyao8910115,Sun Shiyu8910115,Ren Jing12345,Yang Jun12345

Affiliation:

1. Key Lab of In-fiber Integrated Optics

2. Ministry Education of China

3. Harbin Engineering University

4. Harbin 150001

5. China

6. Center of Analysis and Measurement

7. Harbin Institute of Technology

8. Key Laboratory of Materials for High Power Laser

9. Shanghai Institute of Optics and Fine Mechanics

10. CAS

11. Shanghai 201800

Abstract

The partitioning of rare earth ions (REs: Yb3+, Er3+, Eu3+ and Nd3+) in γ-Ga2O3 nanocrystals (NCs) precipitated in a nanostructured silicate glass ceramic is revealed, and the enrichment of REs in the NCs (bulk doping) rather than on the interfaces between the NCs and the surrounding glassy phase (surface doping) is differentiated.

Funder

National Natural Science Foundation of China

Program for New Century Excellent Talents in University

Natural Science Foundation of Heilongjiang Province

Natural Science Foundation of Shanghai

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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